The electrochemical synthesis and corrosion behaviour of TiO2/poly(indole-co-aniline) multilayer coating: Experimental and theoretical approach

dc.contributor.author Toprak Döşlü, Serap
dc.contributor.author Doğru Mert, Başak
dc.contributor.author Yazıcı, Birgül
dc.contributor.author Döşlü, Serap Toprak
dc.contributor.author Mert, Basak Dogru
dc.date.accessioned 2019-05-09T11:33:50Z
dc.date.available 2019-05-09T11:33:50Z
dc.date.issued 2018
dc.description.abstract The aim of this study was to protect stainless steel against corrosion via poly (indole-co-aniline) with the help of titanium dioxide pre-coating. Different monomer ratios (1:1 and 1:9) wereapplied in order to determine the suitable chain composition to synthesize the copolymer in lithiumperchlorate containing acetonitrile. The structures, morphologies, electrochemical properties andcorrosion resistances of the mono and multi-layer coatings were investigated by Fourier-transform infrared spectra, scanning electron microscope, energy dispersive X-ray spectrometer,electrochemical impedance spectroscopy and anodic polarization. Furthermore the geometric struc-ture and electronic properties of indole, aniline, and indole-co-aniline (dimmer) molecules have beeninvestigated by quantum calculations. The results indicated that corrosion protection of copolymerswas increased via titanium dioxide pre-coating. The 1:1 copolymer coating showed better corrosionprevention than 1:9 coating. The correlation was determined between experimental and theoreticalparameters. en_US
dc.description.sponsorship This study has been financially supported by the C ̧ukurovaUniversity research fund. The authors are greatly thankful toC ̧ukurova University Research fund (Project Number:FEF2010D20). en_US
dc.description.sponsorship Cukurova University research fund; Cukurova University Research fund [FEF2010D20]
dc.description.sponsorship Çukurova Üniversitesi, CU, (FEF2010D20); Çukurova Üniversitesi, CU
dc.identifier.citation Döşlü, S. T., Doğru Mert, B., & Yazıcı, B. (2018). The electrochemical synthesis and corrosion behaviour of TiO 2 /poly(indole-co-aniline) multilayer coating: Experimental and theoretical approach. Arabian Journal of Chemistry, 11(1), 1–13. https://doi.org/10.1016/j.arabjc.2017.03.007 en_US
dc.identifier.doi 10.1016/j.arabjc.2017.03.007
dc.identifier.issn 1878-5352
dc.identifier.issn 1878-5379
dc.identifier.scopus 2-s2.0-85017347337
dc.identifier.uri https://hdl.handle.net/20.500.12514/237
dc.identifier.uri https://doi.org/10.1016/j.arabjc.2017.03.007
dc.language.iso en en_US
dc.publisher Arabian Journal of Chemistry en_US
dc.relation.ispartof Arabian Journal of Chemistry
dc.rights info:eu-repo/semantics/openAccess en_US
dc.subject Stainless steel;Polymer;Electrochemical impedancespectroscopy (EIS) en_US
dc.subject Electrochemical Impedance Spectroscopy (EIS)
dc.subject Polymer
dc.subject Stainless Steel
dc.title The electrochemical synthesis and corrosion behaviour of TiO2/poly(indole-co-aniline) multilayer coating: Experimental and theoretical approach en_US
dc.type Article en_US
dspace.entity.type Publication
gdc.author.id Doğru Mert, Başak/0000-0002-2270-9032
gdc.author.scopusid 58677319800
gdc.author.scopusid 55241634100
gdc.author.scopusid 7005398019
gdc.author.wosid YAZICI, Birgül/D-1611-2018
gdc.author.wosid Toprak Döşlü, Serap/AGQ-1130-2022
gdc.coar.access open access
gdc.coar.type text::journal::journal article
gdc.description.department MAÜ, Fakülteler, Sağlık Bilimleri Fakültesi, Beslenme ve Diyetetik Bölümü en_US
gdc.description.departmenttemp [Doslu, Serap Toprak] Mardin Artuklu Univ, Sch Hlth, Dept Nutr & Dietet, Mardin, Turkey; [Mert, Basak Dogru; Yazici, Birgul] Cukurova Univ, Sci & Letters Fac, Dept Chem, TR-01330 Adana, Turkey
gdc.description.endpage 13
gdc.description.issue 1
gdc.description.publicationcategory Kategorisiz en_US
gdc.description.scopusquality Q1
gdc.description.startpage 1
gdc.description.volume 11
gdc.description.woscitationindex Science Citation Index Expanded
gdc.description.wosquality Q2
gdc.identifier.wos WOS:000419598500001
gdc.index.type WoS en_US
gdc.index.type Scopus en_US
gdc.scopus.citedcount 22
gdc.virtual.author Toprak Döşlü, Serap
gdc.virtual.author Doğru Mert, Başak
gdc.wos.citedcount 19
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