Metallo Phthalocyanines bearing 2-Isopropyl-6-methylpyrimidin-4-yloxy Substituents: Synthesis, Characterization, Aggregation Behavior, Antioxidant and Antibacterial Activity, and Electronic Properties

dc.contributor.author Dündar, Abdurrahman
dc.contributor.author Dede, Emrah
dc.contributor.author Gumus, Selcuk
dc.contributor.author Dundar, Abdurrahman
dc.contributor.author Okumus, Veysi
dc.contributor.other 21.02. Department of Medical Services and Techniques / Tıbbi Hizmetler ve Teknikleri Bölümü
dc.contributor.other 21. Vocational School of Health Services / Sağlık Hizmetleri Meslek Yüksekokulu
dc.contributor.other 01. Mardin Artuklu University / Mardin Artuklu Üniversitesi
dc.date.accessioned 14.07.201910:50:10
dc.date.accessioned 2019-07-16T20:44:07Z
dc.date.available 14.07.201910:50:10
dc.date.available 2019-07-16T20:44:07Z
dc.date.issued 2014
dc.description.abstract A novel phthalonitrile derivative bearing 2-isopropyl-6-methylpyrimidin-4-yloxy substituents at peripheral positions was synthesized by a nucleophilic substitution reaction. Metallophthalocyanines were obtained from the reaction of the novel phthalonitrile with metal Zn, Cu, Co, and Ni salts. The characterization of the compounds was performed using elemental analysis as well as UV/Vis, FT-IR, and H-1-NMR spectroscopy. The aggregation behaviors of phthalocyanine complexes were also investigated. These metallophthalocyanines do not show any aggregation behavior between 10 (4)-10 (6) M concentration range in THF. The antioxidant activities of the synthesized compounds were evaluated using three different tests: 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging, metal chelating activity, and reducing power assays. All the compounds exhibited various antioxidant activities. In addition, antimicrobial activity of the compounds was tested over four gram positive and two gram negative bacteria. Moreover, the ground-state geometries of the complexes were optimized using density functional theory (DFT) methods at B3LYP/6-31G(d,p) level in order to obtain information about the 3D arrangements and electronic structure. en_US
dc.identifier.doi 10.1002/zaac.201400129
dc.identifier.issn 0044-2313
dc.identifier.issn 1521-3749
dc.identifier.scopus 2-s2.0-85117547797
dc.identifier.uri https://dx.doi.org/10.1002/zaac.201400129
dc.identifier.uri https://hdl.handle.net/20.500.12514/1402
dc.indekslendigikaynak Web of Science en_US
dc.indekslendigikaynak Scopus en_US
dc.language.iso en en_US
dc.publisher WILEY-V C H VERLAG GMBH en_US
dc.relation.ispartof ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE en_US
dc.rights info:eu-repo/semantics/closedAccess en_US
dc.subject Phthalocyanines en_US
dc.subject Characterization en_US
dc.subject Aggregation en_US
dc.subject Antioxidant activity en_US
dc.subject Antibacterial activity en_US
dc.subject Electronic structure en_US
dc.title Metallo Phthalocyanines bearing 2-Isopropyl-6-methylpyrimidin-4-yloxy Substituents: Synthesis, Characterization, Aggregation Behavior, Antioxidant and Antibacterial Activity, and Electronic Properties en_US
dc.type Article en_US
dspace.entity.type Publication
gdc.description.department [Belirlenecek] en_US
gdc.description.departmenttemp [Agirtas, M. Salih -- Dede, Emrah -- Gumus, Selcuk] Yuzuncu Yil Univ, Fac Sci, Dept Chem, TR-65080 Van, Turkey -- [Dundar, Abdurrahman] Mardin Artuklu Univ, Vocat Higher Sch Hlth Serv, Med Promot & Mkt Program, TR-47000 Mardin, Turkey -- [Okumus, Veysi] Siirt Univ, Fac Arts & Sci, Dept Biol, TR-56100 Siirt, Turkey en_US
gdc.description.endpage 1959 en_US
gdc.description.issue 10 en_US
gdc.description.publicationcategory Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı en_US
gdc.description.scopusquality Q3
gdc.description.startpage 1953 en_US
gdc.description.volume 640 en_US
gdc.description.wosquality Q3
gdc.identifier.wos WOS:000340900200015
gdc.scopus.citedcount 5
gdc.wos.citedcount 6
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